You can only catch a wild Eevee on Route 10. Walk around on the grass and flowers for a 5% to 10% chance of encountering an Eevee. When you encounter an Eevee, weaken its health, and then catch it with a Pokeball. Note: You can do this before defeating the Elite 4.
To evolve an Eevee into a Glaceon or Leafeon, you must be standing next to Ice Rock or Moss Rock when leveling it up. Ice Rock can be found first; it is located in the deepest part of the Frost Cavern (the cave is not too large). Moss Rock is found closer to the end the quest to defeat the Elite 4. It is on Route 20, between Snowbelle City and the Pokemon Village. Enter the area from Snowbelle to immediately see it.
After defeating the Elite 4, one of the three Legendary Birds from the original Pokemon Red and Blue will start appearing throughout Kalos. The bird that appears depends on your starter. If you chose Froakie, it will be Moltres. If you chose Chespin, it will be Articuno. If you chose Fennekin, it will be Zapdos. After encountering one of the birds, check its entry in your Coastal Kalos Pokedex. It will show the bird's current location. You must walk (not fly) to the location and challenge the bird again. After fleeing several times, the bird will eventually retreat to Sea Spirit's Den, finally allowing you the chance to catch it.
Get a Male Plusle with Lightning Rod from a Horde on Route 5, and get a female Pikachu from Route 3 or Santalune Forest. Note: Have a Pokemon with Static to attract more. Put the female Pikachu in the daycare with the male Lightningrod Plusle. Breed a Pikachu until it has Lightning Rod.
Defeat the Elite 4, then return to Pokemon Village. Cross a small stream on the western side using the Surf HM to reach a cave entrance. Mewtwo will be inside immediately after entering the cave. At first, a man will block the cave entrance, but he will disappear once you defeat the Elite 4. Mewtwo is Level 70; use a Master Ball to easily capture him, otherwise it will be a long battle and require a lot of Ultra Balls. As soon as you capture him, you will also get the special stone needed to activate Mewtwo's Mega Evolution.
Pikachu can be found very early in Route 3, immediately after the forest, in small grass patches. Pikachu is a great early Pokemon. He has high special attack and speed stats that give him an advantage early in the game. His special characteristic, Static, works very well early in the game by paralyzing Pokemon that come in contact with him. Pikachu also levels up very quickly early in the game with a lot of bird type Pokemon in the grinding areas. He is overall a great addition to any team early in the game.
To get a Sylveon, you must max out all three stats (Affection, Fullness, and Enjoyment) for an Eevee to evolve it into a Sylveon. To max out all stats for an Eevee, keep petting it and playing the mini-games. It should take approximately one hour to max out all the stats for the Eevee using this method. Note: Make sure to teach the Eevee a Fairy move before leveling it into the Sylveon.
Defeat the Elite 4, then return to Terminus Cave, which is located just off Route 18. The Terminus Cave is one of the longest dungeons in Pokemon X/Y; thus, make sure to have lots of healing items and strong Pokemon before entering it. Zygarde is found in the lowest level of the cave, which is only unlocked after defeating the Elite 4. There are also a few rare items in the lowest level of the cave. Zygarde is Level 70 and dual Dragon and Ground-type; use a Master Ball to easily capture him, otherwise it will be a long battle and require a lot of Ultra Balls.
Heart Scales can be used to teach your Pokemon moves you forgot or never learned at the Move Relearner in Dendemille Town. To get Heart Scales in Pokemon X and Y, you need the Old Rod from Ambrett Town in the Aquarium by the Magikarp Statue and TM46 (Thief), from Cassius's house in Camphier Town. Use the Old Rod on Route 8 - Muraille Coast to battle Luvdiscs, which have a 50% chance of dropping a Heart Scale. Keep fishing for an unlimited amount of Heart Scales. Note: Change spots if Luvdisc does not take the bait.
Select the "Wonder Trade" option, and trade any desired Pokemon to earn some Poke Miles. You get more Poke Miles based on how far away the person you are trading with is from your location. Keep trading the Pokemon you got in Wonder Trade to get more Poke Miles. Use the Poke Miles at the Mileage Club (old man in the white suit) in the Pokemon Center (on South Boulevard) in Lumiose City to buy Rare Candy (500 Poke Miles) and PP Up (1,000 Poke Miles). Rare Candy allows you to increase a Pokemon to the next level, which is very use when they are at a very high level. The PP Up allows you to add an additional move so you can use more moves in battle.
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